Roidipedia.Compound reference & reporting
06 AUG 2026
CompoundsPharmaceutical Perhexiline
PharmaceuticalMetabolic modulatorAnti-anginalCPT-1 inhibitor

Perhexiline

Also known as Pexsig · Perhexiline maleate

A potent metabolic anti-anginal that inhibits carnitine palmitoyltransferase-1 (CPT-1), shifting cardiac metabolism from fatty acids to glucose. Highly effective but with a narrow therapeutic window: it caused hepatotoxicity and peripheral neuropathy in the past, and modern use requires plasma-level monitoring.

01 Overview

Perhexiline inhibits carnitine palmitoyltransferase-1 (and CPT-2), the rate-limiting step of mitochondrial fatty-acid uptake, forcing a metabolic shift toward more oxygen-efficient glucose oxidation. It is one of the most effective anti-anginal drugs for refractory angina and is used in some hypertrophic cardiomyopathy and heart-failure settings.

Its historic reputation was destroyed by cases of hepatotoxicity and disabling peripheral neuropathy, which occurred in slow CYP2D6 metabolisers who accumulated the drug. It fell out of favour but survives in specialist centres (notably Australia and New Zealand) where mandatory therapeutic drug monitoring keeps plasma concentrations within a safe 0.15-0.6 mg/L window.

02 Mechanism

Inhibits carnitine palmitoyltransferase-1 (CPT-1), blocking mitochondrial long-chain fatty-acid uptake and forcing more oxygen-efficient glucose oxidation in the myocardium.

03 Dosing

TierDoseRouteNotes
Starting dose100 mg/dayOral100 mg/day, then adjusted by plasma-level monitoring.

04 Effects

EffectMagnitudeEvidence
Potent anti-anginal effectHighly effective for refractory angina where other agents fail.strongClinical
Symptom relief in HCM/heart failureImproves exercise capacity in selected hypertrophic cardiomyopathy and heart-failure patients.Clinical

05 Side effects

EffectSeverityFrequencyEvidenceCountermeasures
HypoglycaemiaCan lower blood glucose, especially in diabetics on other agents.ModerateUncommonClinical
HepatotoxicityCan cause steatohepatitis and liver injury at supratherapeutic plasma levels.SevereDose/level-dependentClinical
Peripheral neuropathySensorimotor peripheral neuropathy with chronic toxic levels.SevereWith accumulationClinical

07 References

Perhexiline: old drug, new tricks — CPT inhibition and cardiac metabolismCardiovascular Drugs and Therapy, 2007
Perhexiline therapy and drug monitoring in refractory anginaBritish Journal of Clinical Pharmacology

08 Discussion0 comments

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This page is reference information, not medical advice. Doses and protocols are documented as they appear in the clinical literature and in practice — describing them is not a recommendation to use them. Countermeasures listed here are not a substitute for a physician. Legal status varies by jurisdiction and changes.