Roidipedia.Compound reference & reporting
06 AUG 2026
CompoundsAnabolic steroid Penmesterol
Anabolic steroidAndrogenTestosterone derivativeOral17-alpha-alkylated

Penmesterol

Also known as Methyltestosterone 3-cyclopentyl enol ether

Penmesterol is an orally active anabolic-androgenic steroid, a 17-alpha-methyltestosterone derivative bearing a 3-cyclopentyl enol ether, described in older European pharmacological literature. It behaves as a long-acting methyltestosterone-type oral androgen and is of largely historical interest.

01 Overview

Penmesterol is the 3-cyclopentyl enol ether of methyltestosterone, a modification intended to prolong action and improve oral handling. It appeared in mid-20th-century European formularies as an anabolic and androgen-replacement agent.

Human clinical data are scarce, and the compound never gained wide adoption. As a 17-alpha-methylated oral androgen it carries the hepatic and endocrine liabilities of that class; its properties are largely extrapolated from methyltestosterone.

02 Mechanism

Androgen-receptor agonist; a 3-cyclopentyl enol ether prodrug of 17-alpha-methyltestosterone giving oral activity and prolonged action.

03 Dosing

TierDoseRouteNotes
Historical5–25 mg/dayOralApproximate figure from older European references; poorly documented.

Ester comparison

EsterHalf-lifeInjection freq.Testosterone by mass

04 Effects

EffectMagnitudeEvidence
Androgen replacement / anabolicUsed historically for androgen deficiency and anabolic support.unquantifiedAnecdotal
Prolonged oral actionEnol-ether structure was intended to lengthen effect.extended durationPreclinical

05 Side effects

EffectSeverityFrequencyEvidenceCountermeasures
Estrogenic effectsGynaecomastia risk via methyltestosterone's aromatisation to methylestradiol.ModerateExpectedPreclinical
HepatotoxicityCholestasis and enzyme elevation expected from the 17-alkylated methyltestosterone core.SevereClass effectPreclinical

07 References

Enol-ether and ester prodrugs of methyltestosterone: pharmacologyJournal of Steroid Biochemistry (review)

08 Discussion0 comments

?
Sign in to add a comment…
Create account
Discussion is moderated. No sourcing, vendor names or price talk — those comments are removed, and repeat posts are banned.
This page is reference information, not medical advice. Doses and protocols are documented as they appear in the clinical literature and in practice — describing them is not a recommendation to use them. Countermeasures listed here are not a substitute for a physician. Legal status varies by jurisdiction and changes.