Roidipedia.Compound reference & reporting
06 AUG 2026
CompoundsPharmaceutical Endoxifen
PharmaceuticalSERMAnti-estrogenTriphenylethyleneTamoxifen metabolite

Endoxifen

Also known as 4-hydroxy-N-desmethyltamoxifen · (Z)-endoxifen

The potent active metabolite of tamoxifen (4-hydroxy-N-desmethyltamoxifen), formed via CYP2D6. Given directly it bypasses variable tamoxifen metabolism and is under clinical study for breast cancer and mania.

01 Overview

Endoxifen is the major pharmacologically active metabolite of tamoxifen, produced mainly by the liver enzyme CYP2D6. It is roughly 30-100 times more potent than tamoxifen itself at the oestrogen receptor, so patients who are poor CYP2D6 metabolisers derive less benefit from tamoxifen.

Giving endoxifen directly avoids this metabolic variability and has been studied for ER-positive breast cancer and, separately, as a protein kinase C inhibitor in bipolar mania. It represents the 'business end' of tamoxifen for anti-estrogen effect.

02 Mechanism

Active SERM metabolite: high-affinity oestrogen receptor antagonist in breast tissue; also inhibits protein kinase C at higher concentrations, independent of CYP2D6 activation.

03 Dosing

TierDoseRouteNotes
Trial dose1–8 mg/dayOralDoses studied in breast cancer and mania trials.

04 Effects

EffectMagnitudeEvidence
Potent estrogen antagonismDirectly antagonises the breast oestrogen receptor without needing CYP2D6 activation.30-100x tamoxifen potencyClinical
Consistent exposure across metabolisersDelivers active drug regardless of the patient's CYP2D6 genotype.Bypasses CYP2D6 variabilityClinical

05 Side effects

EffectSeverityFrequencyEvidenceCountermeasures
Hot flashesVasomotor symptoms typical of SERMs.MildCommonClinical
Venous thromboembolismTriphenylethylene class clotting risk shared with tamoxifen.SevereRareClinical

07 References

Endoxifen, the active metabolite of tamoxifen, in breast cancerClin Cancer Res

08 Discussion0 comments

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